Chemical Kinetics


The rate of a chemical reaction increases with the increase of temperature. This is described by the Arrhenius eqaution.

k=AeEa/RTk = \mathrm{A} e^{-\mathrm{E_a/R}T}

In the above equation, A\mathrm{A} is the Arrhenius factor or the frequency factor or the pre-exponential factor. It is specific to a given reation. R\mathrm{R} is the gas constant and Ea\mathrm{E_a} is the activation energy measured in joules/mol. The fraction Ea/RT\mathrm{E_a/R}T denotes the fraction of molecules which have the energy greater than the activation energy, the energy required to make a activated complex.